红外光谱法测定尿素生产中脱氢催化剂的 S(Ⅵ)含量

本文介绍一个用红外光谱法测定尿素生产装置内使用过的脱氢催化剂中S(Ⅵ)的含量(以SO_4~-形式存在)。取Al_2(SO_4)_3作标样,溴化钾压片法制备13mm样片,用补偿法测定1120cm~(-1)SO_4~(2-)吸收峰的光密度,绘制A_(1120)～S(Ⅵ)标准曲线。样片中SO_4~(2-)含量在1mg以内符合朗伯—比尔定律。当脱氢催化剂中S(Ⅵ)含量在20％以内,方法准确度为3％,平均偏差最大为0.20。文中并介绍了操作误差的来源及克服办法。     

Effects of nearest and next-nearest neighbour interaction parameters on atomic correlation functions of stepped surfaces

We extend the range of the interaction between the surface scatterers to the next-nearest neighbours and thus treat the stepped surface as a second-order Markov chain. We employ two interaction parameters to describe the behaviour of the atomic pair correlation function for a two-level system and derive an exact expression for this function. This expression is then used to calculate the profile of the diffracted intensity. The effects of the interaction parameters on the intensity profiles as well as on the terrace width distributions are investigated in detail and compared to the molecular beam epitaxy measurement of Si on a Si(111) surface. The physical meaning of the interaction parameters is also interpreted in terms of the Ising model.     

Waveguide modulated non-local optical interaction of semiconductor microdisks

The non-local optical interaction of two semiconductor microdisks with a waveguide bridged at radial direction is proposed and studied by three dimensional finite-difference time-domain （FDTD） electromagnetic simulations. The strong and weak optical interactions between two microdisks are observed and ascribed to the internal coupled modes with different coupling ratios. The vertical radiation losses and the related mode quality factors are modulated by waveguide length and present oscillation characteristics for the resonant modes. In addition, the optical leakage of coupling system is affected by the etching depth of disks due to tile emission of minor components of electric field.     

Experimental characterization and correction of non-equivalence of Solar Irradiance Absolute Radiometer

We experimentally evaluate and correct the non-equivalence between electrical and radiative heating of solar irradiance absolute radiometer to compensate the systematic error of radiant power measurement at ambient pressure. A relative difference of the order of 0.08%-0.27% between electrical and radiative heating sensitivities is shown, and the resulting non-equivalence correction factor is calculated. The radiant power measurement equation is modified using the non-equivalence correction factor, a systematic deviation of 0.19% of radiant power measurement is hence eliminated.     

Solid-state resonant tunneling thermoelectric refrigeration in the cylindrical double-barrier nanostructure

A solid-state thermoelectric refrigerator with a cylindrical InP/InAs/InP double-barrier heterostructure is proposed.Based on the ballistic electron transport and the asymmetrical transmission, we derive the expressions of the performance parameters of this refrigerator. The cooling rate rather than the coefficient of performance is affected by the area of the inner cylinder. Then through the numerical simulation, a triangular cooling rate region is found with respect to the chemical potential and bias voltage; further, that it is because of the small full width at half maximum of the transmission resonance and the linear relationship between the energy position of resonance and the bias voltage. These tunable results might supply some guide to the cooling in tiny components or devices.     

PC synchronization of a class of chaotic systems via event-triggered control

The PC synchronization of a class of chaotic systems is investigated in this paper. The drive system is assumed to have only one state variable available. By constructing proper observers, some novel criteria for PC synchronization are proposed via event-triggered control scheme. The Lu¨ system and Chen system are taken as examples to demonstrate the efficiency of the proposed approach.     

Search for carbon stars and DZ white dwarfs in SDSS spectra survey through machine learning

Carbon stars and DZ white dwarfs are two types of rare objects in the Galaxy.In this paper,we have applied the label propagation algorithm to search for these two types of stars from Data Release Eight(DR8)of the Sloan Digital Sky Survey(SDSS),which is verified to be efcient by calculating precision and recall.From nearly two million spectra including stars,galaxies and QSOs,we have found 260 new carbon stars in which 96 stars have been identified as dwarfs and 7 identified as giants,and 11 composition spectrum systems(each of them consists of a white dwarf and a carbon star).Similarly,using the label propagation method,we have obtained 29 new DZ white dwarfs from SDSS DR8.Compared with PCA reconstructed spectra,the 29 findings are typical DZ white dwarfs.We have also investigated their proper motions by comparing them with proper motion distribution of 9,374 white dwarfs,and found that they satisfy the current observed white dwarfs by SDSS generally have large proper motions.In addition,we have estimated their efective temperatures by fitting the polynomial relationship between efective temperature and g-r color of known DZ white dwarfs,and found 12 of the 29 new DZ white dwarfs are cool,in which nine are between 6,000 K and 6,600 K,and three are below 6,000 K.     

Highly stable amorphous indium‐zinc‐oxide thin‐film transistors with back‐channel wet‐etch process

The stabilities of amorphous indium‐zinc‐oxide (IZO) thin film transistors (TFTs) with back‐channel‐etch (BCE) structure are investigated. A molybdenum (Mo) source/drain electrode was deposited on an IZO layer and patterned by hydrogen peroxide (H₂O₂)‐based etchants. Then, after etching the Mo layer, SF₆ plasma with direct plasma mode was employed and optimized to improve the bias stress stability. Scanning electron microscopy and X‐ray photoelectron spectroscopic analysis revealed that the etching residues were removed efficiently by the plasma treatment. The modified BCE‐ TFTs showed only threshold voltage shifts of 0.25 V and –0.20 V under positive/negative bias thermal stress (P/NBTS, V_GS = ±30 V, V_DS = 0 V and T = 60 °C) after 12 hours, respectively. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Abnormal thermal conductivity of [720]‐oriented BaTiO3 single crystal

The 3ω ‐scanning thermal microscopy and piezoresponse force microscopy techniques were combined to characterize the local thermal conductivity (λ) of ferroelastic domains in [720]‐oriented and [001]‐oriented BaTiO₃ single crystal. The [720]‐oriented BaTiO₃ showed a local λ value of 3.39 W/m·K, while it was 5.95 W/m·K for [001]‐oriented BaTiO₃. The underlying mechanism for such drastic thermal conductivity reduction in [720]‐oriented BaTiO₃ is ascribed to a stronger phonon‐scattering effect due to the high strains appearing in [720]‐oriented BaTiO₃ single crystals. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Effect of pressure on the performance of plasma synthetic jet actuator

The effects of the ambient air pressure level on the performance of plasma synthetic jet actuator have been investigated through electrical and optical diagnostics.Pressures from 1 atm down to 0.1 atm were tested with a 10 Hz excitation.The discharge measurement demonstrates that there is a voltage range to make the actuator work reliably.Higher pressure level needs a higher breakdown voltage,and a higher discharge current and energy deposition are produced.But when the actuator works with the maximum breakdown voltage,the fraction of the initial capacitor energy delivered to the arc is almost invariable.This preliminary study also confirms the effectiveness of the plasma synthetic jet at low pressure.Indeed,the maximum velocities of the precursor shock and the plasma jet induced by the actuator with maximum breakdown voltage are independent of the ambient pressure level;reach about 530 and 460 m/s respectively.The mass flux of the plasma jet increases with ambient pressure increasing,but the strength of the precursor shock presents a local maximum at 0.6 atm.